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''The unidentified substance in this sample has a different molecular ion, but shares a major fragment with N-methyl-Pinoline at 173.0, and another at 156. It would be plausible that it could be N-ethyl-Pinoline, from the MS alone. That would have a molecular ion of ~230.25, and the ethyl would fall off in the same way the methyl does.'' (Thanks, Borax!)
This identification is seconded by Y. (Thanks Y.!)